{"id":7235,"date":"2024-09-10T14:11:11","date_gmt":"2024-09-10T06:11:11","guid":{"rendered":"https:\/\/www.newtopchem.cn\/?p=7235"},"modified":"2024-09-10T14:19:36","modified_gmt":"2024-09-10T06:19:36","slug":"%e4%b8%89%e4%b8%81%e5%9f%ba%e6%b0%a7%e5%8c%96%e9%94%a1%e7%9a%84%e5%8c%96%e5%ad%a6%e6%80%a7%e8%b4%a8%e5%8f%8a%e5%85%b6%e5%9c%a8%e6%9d%90%e6%96%99%e7%a7%91%e5%ad%a6%e4%b8%ad%e7%9a%84%e4%bd%9c%e7%94%a8","status":"publish","type":"post","link":"https:\/\/www.newtopchem.cn\/7235.html","title":{"rendered":"\u4e09\u4e01\u57fa\u6c27\u5316\u9521\u7684\u5316\u5b66\u6027\u8d28\u53ca\u5176\u5728\u6750\u6599\u79d1\u5b66\u4e2d\u7684\u4f5c\u7528"},"content":{"rendered":"

\u5f15\u8a00
\n\u4e09\u4e01\u57fa\u6c27\u5316\u9521\uff08tributyltin oxide, TBT\uff09\u662f\u4e00\u79cd\u91cd\u8981\u7684\u6709\u673a\u91d1\u5c5e\u5316\u5408\u7269\uff0c\u56e0\u5176\u72ec\u7279\u7684\u5316\u5b66\u6027\u8d28\u800c\u5728\u591a\u4e2a\u9886\u57df\u5f97\u5230\u5e94\u7528\u3002\u672c\u6587\u5c06\u63a2\u8ba8\u4e09\u4e01\u57fa\u6c27\u5316\u9521\u7684\u57fa\u672c\u5316\u5b66\u6027\u8d28\uff0c\u5e76\u91cd\u70b9\u5206\u6790\u5176\u5728\u6750\u6599\u79d1\u5b66\u4e2d\u7684\u5e94\u7528\u4e0e\u4f5c\u7528\u3002<\/p>\n

\u4e00\u3001\u4e09\u4e01\u57fa\u6c27\u5316\u9521\u7684\u57fa\u672c\u5316\u5b66\u6027\u8d28
\n\u4e09\u4e01\u57fa\u6c27\u5316\u9521\uff08\u5316\u5b66\u5f0f\uff1aC12H27SnO\uff09\u662f\u4e00\u79cd\u65e0\u8272\u6216\u6de1\u9ec4\u8272\u7684\u6db2\u4f53\uff0c\u5206\u5b50\u91cf\u7ea6\u4e3a289.67 g\/mol\u3002\u5176\u7269\u7406\u5316\u5b66\u6027\u8d28\u5305\u62ec\u4ee5\u4e0b\u51e0\u4e2a\u65b9\u9762\uff1a<\/p>\n

\u6eb6\u89e3\u6027\uff1aTBT\u6613\u6eb6\u4e8e\u591a\u6570\u6709\u673a\u6eb6\u5242\uff0c\u5982\u3001\u4e59\u9187\u3001\u7b49\uff0c\u4f46\u51e0\u4e4e\u4e0d\u6eb6\u4e8e\u6c34\u3002
\n\u70ed\u7a33\u5b9a\u6027\uff1aTBT\u5728\u8f83\u4f4e\u6e29\u5ea6\u4e0b\u76f8\u5bf9\u7a33\u5b9a\uff0c\u4f46\u5728\u9ad8\u6e29\u4e0b\u5bb9\u6613\u5206\u89e3\u3002
\n\u53cd\u5e94\u6d3b\u6027\uff1a\u4f5c\u4e3a\u4e00\u79cd\u6709\u673a\u91d1\u5c5e\u5316\u5408\u7269\uff0cTBT\u5177\u6709\u8f83\u9ad8\u7684\u53cd\u5e94\u6d3b\u6027\uff0c\u80fd\u591f\u53c2\u4e0e\u591a\u79cd\u6709\u673a\u5408\u6210\u53cd\u5e94\u3002
\n\u4e8c\u3001\u4e09\u4e01\u57fa\u6c27\u5316\u9521\u7684\u5408\u6210\u4e0e\u5236\u5907
\nTBT\u53ef\u4ee5\u901a\u8fc7\u591a\u79cd\u9014\u5f84\u5408\u6210\uff0c\u5e38\u89c1\u7684\u662f\u901a\u8fc7\u4e09\u4e01\u57fa\u6c2f\u5316\u9521\u4e0e\u6c22\u6c27\u5316\u94a0\u6216\u78b3\u9178\u94a0\u5728\u6709\u673a\u6eb6\u5242\u4e2d\u53cd\u5e94\u5236\u5f97\u3002\u53cd\u5e94\u65b9\u7a0b\u5f0f\u5982\u4e0b\uff1a<\/p>\n

Bu
\n3
\nSnCl
\n+
\nNaOH
\n\u2192
\nBu
\n3
\nSnO
\n+
\nNaCl
\nBu
\n3
\n\u200b
\nSnCl+NaOH\u2192Bu
\n3
\n\u200b
\nSnO+NaCl<\/p>\n

\u4e09\u3001\u4e09\u4e01\u57fa\u6c27\u5316\u9521\u5728\u6750\u6599\u79d1\u5b66\u4e2d\u7684\u5e94\u7528
\nTBT\u56e0\u5176\u72ec\u7279\u7684\u5316\u5b66\u6027\u8d28\uff0c\u5728\u6750\u6599\u79d1\u5b66\u9886\u57df\u5c55\u73b0\u51fa\u5e7f\u6cdb\u7684\u5e94\u7528\u4ef7\u503c\u3002<\/p>\n

3.1 \u50ac\u5316\u5242
\n\u5728\u6709\u673a\u5408\u6210\u4e2d\uff0cTBT\u53ef\u4ee5\u4f5c\u4e3a\u50ac\u5316\u5242\u53c2\u4e0e\u591a\u79cd\u53cd\u5e94\uff0c\u5982\u5076\u8054\u53cd\u5e94\u3001\u805a\u5408\u53cd\u5e94\u7b49\u3002\u5b83\u80fd\u591f\u52a0\u901f\u53cd\u5e94\u8fdb\u7a0b\uff0c\u63d0\u9ad8\u4ea7\u7269\u7684\u9009\u62e9\u6027\u548c\u6536\u7387\u3002<\/p>\n

3.2 \u529f\u80fd\u6027\u6d82\u5c42
\nTBT\u5728\u6d82\u6599\u884c\u4e1a\u4e2d\u88ab\u7528\u4f5c\u9632\u6c61\u5242\uff0c\u53ef\u4ee5\u9632\u6b62\u6d77\u6d0b\u751f\u7269\u9644\u7740\u5728\u8239\u8236\u8868\u9762\u3002\u6b64\u5916\uff0c\u5b83\u8fd8\u53ef\u4ee5\u4f5c\u4e3a\u6297\u83cc\u5242\u6dfb\u52a0\u5230\u6d82\u6599\u4e2d\uff0c\u589e\u5f3a\u6d82\u5c42\u7684\u6297\u83cc\u6027\u80fd\u3002<\/p>\n

3.3 \u9676\u74f7\u6750\u6599
\nTBT\u5728\u5236\u5907\u91d1\u5c5e\u6c27\u5316\u7269\u9676\u74f7\u6750\u6599\u65f6\u4f5c\u4e3a\u524d\u9a71\u4f53\u4f7f\u7528\u3002\u901a\u8fc7\u6c34\u89e3\u548c\u51dd\u80f6\u5316\u8fc7\u7a0b\uff0cTBT\u53ef\u4ee5\u8f6c\u5316\u4e3aSnO2\u7eb3\u7c73\u7c92\u5b50\uff0c\u8fd9\u4e9b\u7c92\u5b50\u53ef\u7528\u4e8e\u5236\u5907\u9ad8\u6027\u80fd\u7684\u534a\u5bfc\u4f53\u9676\u74f7\u6750\u6599\u3002<\/p>\n

3.4 \u7535\u5b50\u6750\u6599
\nTBT\u53ef\u4ee5\u4f5c\u4e3a\u539f\u6599\u5236\u5907\u5bfc\u7535\u6027\u826f\u597d\u7684\u9521\u6c27\u5316\u7269\u8584\u819c\uff0c\u8fd9\u7c7b\u8584\u819c\u5728\u5149\u7535\u8f6c\u6362\u5668\u4ef6\u3001\u6c14\u4f53\u4f20\u611f\u5668\u7b49\u9886\u57df\u6709\u91cd\u8981\u5e94\u7528\u3002\u901a\u8fc7\u63a7\u5236\u6c89\u79ef\u6761\u4ef6\uff0c\u53ef\u4ee5\u83b7\u5f97\u5177\u6709\u826f\u597d\u7ed3\u6676\u5ea6\u548c\u5747\u5300\u6027\u7684\u8584\u819c\u3002<\/p>\n

3.5 \u7eb3\u7c73\u6280\u672f
\n\u5229\u7528TBT\u4f5c\u4e3a\u524d\u9a71\u4f53\uff0c\u53ef\u4ee5\u901a\u8fc7\u6eb6\u80f6-\u51dd\u80f6\u6cd5\u3001\u5316\u5b66\u6c14\u76f8\u6c89\u79ef\u7b49\u6280\u672f\u5236\u5907\u7eb3\u7c73\u7ea7\u7684\u9521\u6c27\u5316\u7269\u6750\u6599\u3002\u8fd9\u4e9b\u7eb3\u7c73\u6750\u6599\u5177\u6709\u9ad8\u7684\u6bd4\u8868\u9762\u79ef\u548c\u826f\u597d\u7684\u5316\u5b66\u7a33\u5b9a\u6027\uff0c\u5728\u50ac\u5316\u5242\u3001\u7535\u6c60\u7535\u6781\u6750\u6599\u7b49\u65b9\u9762\u5177\u6709\u6f5c\u5728\u7684\u5e94\u7528\u4ef7\u503c\u3002<\/p>\n

\u56db\u3001\u4e09\u4e01\u57fa\u6c27\u5316\u9521\u5728\u6750\u6599\u79d1\u5b66\u4e2d\u7684\u4f5c\u7528\u673a\u5236
\nTBT\u5728\u6750\u6599\u79d1\u5b66\u4e2d\u7684\u5e94\u7528\u4e0e\u5176\u5316\u5b66\u6027\u8d28\u5bc6\u5207\u76f8\u5173\u3002\u4ee5\u4e0b\u662f\u4e00\u4e9b\u5178\u578b\u5e94\u7528\u7684\u4f5c\u7528\u673a\u5236\uff1a<\/p>\n

\u50ac\u5316\u4f5c\u7528\uff1aTBT\u4f5c\u4e3a\u50ac\u5316\u5242\u65f6\uff0c\u53ef\u4ee5\u901a\u8fc7\u63d0\u4f9b\u6d3b\u6027\u4e2d\u5fc3\u6765\u964d\u4f4e\u53cd\u5e94\u6d3b\u5316\u80fd\uff0c\u4ece\u800c\u52a0\u5feb\u53cd\u5e94\u901f\u7387\u3002
\n\u6d82\u5c42\u529f\u80fd\uff1a\u4f5c\u4e3a\u6d82\u5c42\u6210\u5206\u65f6\uff0cTBT\u80fd\u591f\u901a\u8fc7\u5176\u5316\u5b66\u6d3b\u6027\u963b\u6b62\u751f\u7269\u9644\u7740\uff0c\u540c\u65f6\u8d4b\u4e88\u6d82\u5c42\u6297\u83cc\u6027\u80fd\u3002
\n\u7eb3\u7c73\u6750\u6599\u5408\u6210\uff1aTBT\u4f5c\u4e3a\u524d\u9a71\u4f53\u65f6\uff0c\u901a\u8fc7\u6c34\u89e3\u6216\u70ed\u89e3\u751f\u6210\u76f8\u5e94\u7684\u91d1\u5c5e\u6c27\u5316\u7269\u7eb3\u7c73\u9897\u7c92\uff0c\u8fd9\u4e9b\u9897\u7c92\u5177\u6709\u72ec\u7279\u7684\u5149\u5b66\u3001\u7535\u5b66\u7b49\u6027\u8d28\u3002
\n\u4e94\u3001\u73af\u5883\u4e0e\u5b89\u5168\u8003\u8651
\n\u5c3d\u7ba1TBT\u5728\u6750\u6599\u79d1\u5b66\u4e2d\u6709\u5e7f\u6cdb\u7684\u5e94\u7528\uff0c\u4f46\u5176\u5bf9\u73af\u5883\u7684\u5f71\u54cd\u4e5f\u4e0d\u5bb9\u5ffd\u89c6\u3002TBT\u5177\u6709\u4e00\u5b9a\u7684\u751f\u7269\u7d2f\u79ef\u6027\uff0c\u957f\u671f\u66b4\u9732\u53ef\u80fd\u5bf9\u6c34\u751f\u751f\u6001\u7cfb\u7edf\u9020\u6210\u5371\u5bb3\u3002\u56e0\u6b64\uff0c\u5728\u4f7f\u7528TBT\u65f6\u9700\u8981\u91c7\u53d6\u9002\u5f53\u7684\u73af\u5883\u4fdd\u62a4\u63aa\u65bd\uff0c\u5e76\u63a2\u7d22\u66f4\u73af\u4fdd\u7684\u66ff\u4ee3\u54c1\u3002<\/p>\n

\u516d\u3001\u7ed3\u8bba
\n\u4e09\u4e01\u57fa\u6c27\u5316\u9521\u4f5c\u4e3a\u4e00\u79cd\u591a\u529f\u80fd\u7684\u6709\u673a\u91d1\u5c5e\u5316\u5408\u7269\uff0c\u5728\u6750\u6599\u79d1\u5b66\u9886\u57df\u5c55\u73b0\u51fa\u4e86\u5de8\u5927\u7684\u5e94\u7528\u6f5c\u529b\u3002\u901a\u8fc7\u5bf9\u5176\u5316\u5b66\u6027\u8d28\u7684\u6df1\u5165\u4e86\u89e3\uff0c\u53ef\u4ee5\u66f4\u597d\u5730\u5229\u7528TBT\u7684\u4f18\u52bf\uff0c\u5f00\u53d1\u51fa\u66f4\u591a\u9ad8\u6027\u80fd\u7684\u6750\u6599\u3002\u7136\u800c\uff0c\u5728\u8ffd\u6c42\u6280\u672f\u521b\u65b0\u7684\u540c\u65f6\uff0c\u4e5f\u9700\u8981\u5173\u6ce8\u5176\u53ef\u80fd\u5e26\u6765\u7684\u73af\u5883\u548c\u5065\u5eb7\u98ce\u9669\uff0c\u5bfb\u6c42\u53ef\u6301\u7eed\u53d1\u5c55\u7684\u89e3\u51b3\u65b9\u6848\u3002
\n\u6269\u5c55\u9605\u8bfb\uff1a<\/p>\n

cyclohexylamine<\/u><\/a><\/p>\n

Tetrachloroethylene Perchloroethylene CAS:127-18-4<\/u><\/a><\/p>\n

NT CAT DMDEE<\/u><\/a><\/p>\n

NT CAT PC-5<\/u><\/a><\/p>\n

N-Methylmorpholine<\/u><\/a><\/p>\n

4-Formylmorpholine<\/u><\/a><\/p>\n

Toyocat TE tertiary amine catalyst Tosoh<\/u><\/a><\/p>\n

Toyocat RX5 catalyst trimethylhydroxyethyl ethylenediamine Tosoh<\/u><\/a><\/p>\n

NT CAT DMP-30<\/u><\/a><\/p>\n

NT CAT DMEA<\/u><\/a><\/p>\n","protected":false},"excerpt":{"rendered":"

\u5f15\u8a00 \u4e09\u4e01\u57fa\u6c27\u5316\u9521\uff08tributyltin oxide, TBT\uff09\u662f\u4e00\u79cd\u91cd\u8981\u7684\u6709\u673a\u91d1\u5c5e\u5316\u5408\u7269\uff0c\u56e0\u5176\u72ec\u7279\u7684\u5316\u5b66\u6027\u8d28\u800c\u5728\u591a\u4e2a\u9886\u57df\u5f97\u5230\u5e94\u7528\u3002\u672c\u6587\u5c06\u63a2\u8ba8\u4e09\u4e01\u57fa\u6c27\u5316\u9521\u7684\u57fa\u672c\u5316\u5b66\u6027\u8d28\uff0c\u5e76\u91cd\u70b9\u5206\u6790\u5176\u5728\u6750\u6599\u79d1\u5b66\u4e2d\u7684\u5e94\u7528\u4e0e\u4f5c\u7528\u3002 \u4e00\u3001\u4e09\u4e01\u57fa\u6c27\u5316\u9521\u7684\u57fa\u672c\u5316\u5b66\u6027\u8d28 \u4e09\u4e01\u57fa\u6c27\u5316\u9521\uff08\u5316\u5b66\u5f0f\uff1aC12H27SnO\uff09\u662f\u4e00\u79cd\u65e0\u8272\u6216\u6de1\u9ec4\u8272\u7684\u6db2\u4f53\uff0c\u5206\u5b50\u91cf\u7ea6 …<\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":[],"categories":[2],"tags":[],"_links":{"self":[{"href":"https:\/\/www.newtopchem.cn\/wp-json\/wp\/v2\/posts\/7235"}],"collection":[{"href":"https:\/\/www.newtopchem.cn\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/www.newtopchem.cn\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/www.newtopchem.cn\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/www.newtopchem.cn\/wp-json\/wp\/v2\/comments?post=7235"}],"version-history":[{"count":2,"href":"https:\/\/www.newtopchem.cn\/wp-json\/wp\/v2\/posts\/7235\/revisions"}],"predecessor-version":[{"id":7239,"href":"https:\/\/www.newtopchem.cn\/wp-json\/wp\/v2\/posts\/7235\/revisions\/7239"}],"wp:attachment":[{"href":"https:\/\/www.newtopchem.cn\/wp-json\/wp\/v2\/media?parent=7235"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/www.newtopchem.cn\/wp-json\/wp\/v2\/categories?post=7235"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/www.newtopchem.cn\/wp-json\/wp\/v2\/tags?post=7235"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}